People have come to understand the enormous impacts-beneficial as well as harmful-plastics have on human lives and the environment. As polymer(聚合物) scientists committed to inventing sustainable solutions for real-world problems, we set out to tackle the issue of plastic waste by rethinking the way polymers are designed so we could make plastics with recyclability built right in.
Everyday items including milk jug, grocery bags, and takeout containers are made from a class of polymers called polyolefins. These plastics are really durable (耐用的) because the chemical bonds in those polymers are extremely stable. In a world set up for disposable (一次性的) items, durability is no longer a design feature but rather a design drawback. Imagine if half the plastics used today were recyclable through twice as many processes as they are now. Also conventional recycling requires careful sorting of all the collected materials, which can be challenging with so many different plastics. For example, separating paper from metal doesn't require complex technology, but sorting a container from a milk jug of a different polyolefin is difficult to do without the occasional mistake.
In a study published in Science in October 2023, we described a series of polymers with only two building blocks-one soft polymer and one hard polymer-that behave like polyolefins but could be chemically recycled. Connecting two different polymers multiple times until they form a single, long molecule(分子) creates what's called a multiblock polymer. By changing how much of each polymer type goes into the multiblock polymer, our team produced a wide range of materials with properties that covered all polyolefin types.
Using the same strategy but by adding hydrogen, we could disconnect the polymers back into their building blocks and easily separate them to use again. When we made new polymers out of these recycled plastics, they performed just as well as the original materials even after several rounds of chemical recycling. So we were able to create materials with similar properties of the plastics the world relies on. We believe this work is a step toward more sustainable plastics.