二氧化碳催化加氢制取二甲醚(DME)有利于减少温室气体二氧化碳,制取过程发生如下反应:反应Ⅰ.![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmsub%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%E2%87%8C%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3EOH%3C%2Fmtext%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmi+mathvariant%3D%22normal%22%3E%EF%BC%9B%3C%2Fmi%3E%3Cmi+mathvariant%3D%22normal%22%3E%CE%94%3C%2Fmi%3E%3Cmsub%3E%3Cmi%3EH%3C%2Fmi%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
反应Ⅱ.![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3EOH%3C%2Fmtext%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%E2%87%8C%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EOCH%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmi+mathvariant%3D%22normal%22%3E%EF%BC%9B%3C%2Fmi%3E%3Cmi+mathvariant%3D%22normal%22%3E%CE%94%3C%2Fmi%3E%3Cmsub%3E%3Cmi%3EH%3C%2Fmi%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E23.4%3C%2Fmn%3E%3Cmtext%3EkJ%3C%2Fmtext%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3Emol%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
反应Ⅲ.![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%E2%87%8C%3C%2Fmo%3E%3Cmtext%3ECO%3C%2Fmtext%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmfenced+close%3D%22%29%22+open%3D%22%28%22%3E%3Cmtext%3Eg%3C%2Fmtext%3E%3C%2Fmfenced%3E%3Cmi+mathvariant%3D%22normal%22%3E%EF%BC%9B%3C%2Fmi%3E%3Cmi+mathvariant%3D%22normal%22%3E%CE%94%3C%2Fmi%3E%3Cmsub%3E%3Cmi%3EH%3C%2Fmi%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E41.17%3C%2Fmn%3E%3Cmtext%3EkJ%3C%2Fmtext%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3Emol%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
回答下列问题:
①
时,向恒压容器中充入
和
, 若在该条件下只发生反应Ⅰ,达平衡时,放出
能量;若向相同容器中充入
和
, 达平衡时,吸收
能量,则反应Ⅰ的![](https://math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmi+mathvariant%3D%22normal%22%3E%CE%94%3C%2Fmi%3E%3Cmsub%3E%3Cmi%3EH%3C%2Fmi%3E%3Cmn%3E1%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%3D%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
。
②在压强一定的条件下,将
和
按一定比例、流速通过装有催化剂的反应管,测得“
转化率”及“
选择性”和“
、
选择性的和”分别与温度的关系如图所示。(
选择性=
)
![](http://tikupic.21cnjy.com/ct20241o/6f/b9/6fb95a97b333f82a6816b8e0c2a99d53.png)
ⅰ.曲线C表示。
ⅱ.温度
之间,升高温度,比值
将(填“增大”“减小”或“不变”)。